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This is a two-story building attached to a three-story building. The first floor of the two-story building is mostly caved-in, allowing little room inside. This was the original liquor store. The Gunners have set-up a saloon in the attached three-story building, with access by means of scaffolding. A chemistry station is inside as well as liquor, etc. The upper levels are not accessible from below.
Quincy Liquors appears only in Fallout 4.