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In Fallout, it can be gifted as a reward for the quest, Help Irwin in the Hub. In Fallout 2, it is buy-able in NCR, New Reno (special stock in New Reno Arms), San Francisco or you can get it from the random encounter "A gang" in the New Reno area.The pistol's appearance is a reference to Deckard's handgun in the movie Blade Runner.
The Highwayman has got a full analog system, 800+ Horsepower, 0 to 60 in less than a second, a sizeable trunk and spacious interior, able to accomodate the entire party of the Chosen One, from Marcus to Skynet. That particular Highwayman could be found in the Den. Its missing part, the fuel cell controller, could be found in Gecko.The battery can be charged with either microfusion cells or small energy cells.
Bottle caps are backed by The Hub merchants. The reasoning for their support is that the technology to manufacture bottle caps and paint the surface has been lost in the Great War, which would greatly limit any counterfeiting efforts. Secondly, there is a limited number of bottle caps, which would serve to preserve their value to some degree.The issue of some concern is that with time, number of bottle caps will decrease due to wear.