Detect Lies is a perk from Van Buren, the canceled Fallout 3 project by Black Isle.
Coleridge would have made use of this perk. It would have enabled him to see through most of the Prisoner's Deception, regardless of how well they might have been disguised.
Sources
Van Buren B.O.M.B.-001 design document
Template:Navbox perks VB