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After you receive the quest from Mags Black , you'll be given a target to collar. This target may be in a city or settlement, which will turn hostile if you collar your target in broad daylight. You have the option, with a minor speech check, to ask the target to follow you. Lead them away from people to avoid having to kill anyone. Speak to them again and the best choice is an easy speech check telling them you have a necklace they would look good in and collaring them. Other options are to sneak up on your target and to collar them, or to beat them into submission and collar them while they are stunned. Be careful that any follower you might have doesn't kill your target if you choose the violent option.
Return to Mags Black for a reward.
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